Physical Chemistry
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Atomic Structure and Periodic Trends
Atomic Structure and Periodic Trends - Advanced Concepts
Atomic Structure and Periodic Trends - Applications
Atomic Structure and Periodic Trends - Case Studies
Atomic Structure and Periodic Trends - Competitive Exam Level
Atomic Structure and Periodic Trends - Higher Difficulty Problems
Atomic Structure and Periodic Trends - Numerical Applications
Atomic Structure and Periodic Trends - Problem Set
Atomic Structure and Periodic Trends - Real World Applications
Chemical Bonding and Molecular Structure
Chemical Bonding and Molecular Structure - Advanced Concepts
Chemical Bonding and Molecular Structure - Applications
Chemical Bonding and Molecular Structure - Case Studies
Chemical Bonding and Molecular Structure - Competitive Exam Level
Chemical Bonding and Molecular Structure - Higher Difficulty Problems
Chemical Bonding and Molecular Structure - Numerical Applications
Chemical Bonding and Molecular Structure - Problem Set
Chemical Bonding and Molecular Structure - Real World Applications
Chemical Equilibrium (Le Chateliers Principle)
Chemical Equilibrium (Le Chateliers Principle) - Advanced Concepts
Chemical Equilibrium (Le Chateliers Principle) - Applications
Chemical Equilibrium (Le Chateliers Principle) - Case Studies
Chemical Equilibrium (Le Chateliers Principle) - Competitive Exam Level
Chemical Equilibrium (Le Chateliers Principle) - Higher Difficulty Problems
Chemical Equilibrium (Le Chateliers Principle) - Numerical Applications
Chemical Equilibrium (Le Chateliers Principle) - Problem Set
Chemical Equilibrium (Le Chateliers Principle) - Real World Applications
Chemical Kinetics and Reaction Rates
Chemical Kinetics and Reaction Rates - Advanced Concepts
Chemical Kinetics and Reaction Rates - Applications
Chemical Kinetics and Reaction Rates - Case Studies
Chemical Kinetics and Reaction Rates - Competitive Exam Level
Chemical Kinetics and Reaction Rates - Higher Difficulty Problems
Chemical Kinetics and Reaction Rates - Numerical Applications
Chemical Kinetics and Reaction Rates - Problem Set
Chemical Kinetics and Reaction Rates - Real World Applications
Electrochemistry Basics
Electrochemistry Basics - Advanced Concepts
Electrochemistry Basics - Applications
Electrochemistry Basics - Case Studies
Electrochemistry Basics - Competitive Exam Level
Electrochemistry Basics - Higher Difficulty Problems
Electrochemistry Basics - Numerical Applications
Electrochemistry Basics - Problem Set
Electrochemistry Basics - Real World Applications
States of Matter and Gas Laws
States of Matter and Gas Laws - Advanced Concepts
States of Matter and Gas Laws - Applications
States of Matter and Gas Laws - Case Studies
States of Matter and Gas Laws - Competitive Exam Level
States of Matter and Gas Laws - Higher Difficulty Problems
States of Matter and Gas Laws - Numerical Applications
States of Matter and Gas Laws - Problem Set
States of Matter and Gas Laws - Real World Applications
Thermodynamics and Enthalpy
Thermodynamics and Enthalpy - Advanced Concepts
Thermodynamics and Enthalpy - Applications
Thermodynamics and Enthalpy - Case Studies
Thermodynamics and Enthalpy - Competitive Exam Level
Thermodynamics and Enthalpy - Higher Difficulty Problems
Thermodynamics and Enthalpy - Numerical Applications
Thermodynamics and Enthalpy - Problem Set
Thermodynamics and Enthalpy - Real World Applications
Q. A chemical reaction releases 250 J of heat. If the reaction occurs at constant pressure, what is the change in enthalpy?
Q. A process absorbs 300 J of heat and does 100 J of work. What is the change in internal energy (ΔU)?
Q. A reaction has an enthalpy change of 200 kJ for the formation of 1 mole of product. What is the enthalpy change for the formation of 0.5 moles of product?
Q. According to Graham's Law, how does the rate of effusion of a gas relate to its molar mass?
Q. According to Graham's Law, the rate of effusion of a gas is inversely proportional to what?
Q. According to the Kinetic Molecular Theory, which of the following is NOT a postulate?
Q. At constant temperature, what happens to the pressure of a gas if its volume is doubled?
Q. At constant temperature, what happens to the pressure of a gas if its volume is halved?
Q. At what temperature does the Kelvin scale start?
Q. Calculate the change in enthalpy (ΔH) when 2 moles of a substance absorb 500 J of heat at constant pressure.
Q. Calculate the dipole moment of a molecule with a charge of 1.6 x 10^-19 C and a bond length of 1.5 Å.
Q. Calculate the dipole moment of HCl given that the bond length is 1.27 Å and the charge separation is 0.33 e.
Q. Calculate the enthalpy change (ΔH) for the reaction: 2NO(g) + O2(g) → 2NO2(g) given the following bond enthalpies: N≡N = 941 kJ/mol, O=O = 498 kJ/mol, N=O = 201 kJ/mol.
Q. Calculate the formal charge on a nitrogen atom in NH3.
Q. Calculate the formal charge on the nitrogen atom in NO3-.
Q. Calculate the Gibbs free energy change (ΔG) for a cell with E° = 0.75 V and n = 2 moles of electrons transferred.
Q. Calculate the ionization energy of hydrogen in eV if the energy level is -13.6 eV.
Q. Calculate the ionization energy of hydrogen in eV if the energy of the electron in the ground state is -13.6 eV.
Q. Determine the bond angle in a tetrahedral molecule like CH4.
Q. For a first-order reaction, if the half-life is 10 minutes, what is the rate constant?
Q. For a first-order reaction, if the half-life is 10 minutes, what will be the half-life if the concentration is doubled?
Q. For a molecule with a bond length of 1.2 Å and a bond order of 2, what is the bond energy in kJ/mol?
Q. For a reaction A → B, if the rate constant k is 0.1 s^-1, what is the time required for the concentration of A to decrease to 25% of its initial value?
Q. For a reaction at equilibrium, if the concentration of products is increased, what will happen to the position of equilibrium according to Le Chatelier's principle?
Q. For a reaction at equilibrium, if the temperature is increased and ΔH is positive, what will happen to the position of equilibrium?
Q. For a reaction at equilibrium, what happens if the concentration of a reactant is increased?
Q. For a reaction that follows first-order kinetics, what is the relationship between the rate constant and the half-life?
Q. For a reaction that is first order in A and second order in B, what is the overall order of the reaction?
Q. For a reaction with a negative ΔH and a positive ΔS, what can be said about the spontaneity at high temperatures?
Q. For a reaction with a rate constant of 0.1 s^-1, what is the half-life for a first-order reaction?