Physical Chemistry

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Q. In a reaction where the rate law is rate = k[A]^2[B], what is the overall order of the reaction?
  • A. 1
  • B. 2
  • C. 3
  • D. 4
Q. In a reaction with a rate constant k, if the concentration of reactant A is doubled, how does the rate change if the reaction is second order with respect to A?
  • A. Rate remains the same
  • B. Rate doubles
  • C. Rate quadruples
  • D. Rate increases by a factor of eight
Q. In a reaction with a rate constant of 0.03 s^-1, how long will it take for the concentration to decrease to 25% of its initial value?
  • A. 23.1 s
  • B. 46.2 s
  • C. 69.3 s
  • D. 92.4 s
Q. In a redox reaction, if the oxidation state of manganese changes from +7 to +2, how many electrons are gained?
  • A. 5
  • B. 3
  • C. 2
  • D. 7
Q. In a reversible isothermal expansion of an ideal gas, what is the work done by the gas?
  • A. W = nRT ln(Vf/Vi)
  • B. W = nRT (Vf - Vi)
  • C. W = -PΔV
  • D. W = 0
Q. In a system at equilibrium, what is the effect of decreasing the volume of the container?
  • A. Shifts to the side with more moles of gas
  • B. Shifts to the side with fewer moles of gas
  • C. No effect
  • D. Increases the temperature
Q. In a zero-order reaction, how does the concentration of reactant affect the rate?
  • A. Rate increases with concentration
  • B. Rate decreases with concentration
  • C. Rate is constant regardless of concentration
  • D. Rate is inversely proportional to concentration
Q. In a zero-order reaction, how does the concentration of the reactant affect the rate?
  • A. Rate is directly proportional to concentration
  • B. Rate is inversely proportional to concentration
  • C. Rate is independent of concentration
  • D. Rate is proportional to the square of concentration
Q. In a zero-order reaction, how does the concentration of the reactant change over time?
  • A. Linearly with time
  • B. Exponentially with time
  • C. Inversely with time
  • D. Remains constant
Q. In a zero-order reaction, how does the rate change with respect to the concentration of the reactant?
  • A. Rate increases
  • B. Rate decreases
  • C. Rate is constant
  • D. Rate is zero
Q. In a zero-order reaction, how does the rate of reaction change with respect to the concentration of the reactant?
  • A. Rate increases with concentration
  • B. Rate decreases with concentration
  • C. Rate is constant regardless of concentration
  • D. Rate is zero
Q. In an electrochemical cell, what is the anode?
  • A. Site of oxidation
  • B. Site of reduction
  • C. Site of electron gain
  • D. Site of ion formation
Q. In an endothermic reaction, what happens to the enthalpy of the system?
  • A. Increases
  • B. Decreases
  • C. Remains constant
  • D. Fluctuates
Q. In an endothermic reaction, what is the sign of ΔH?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Undefined
Q. In an exothermic reaction at equilibrium, what effect does increasing the temperature have?
  • A. Shifts equilibrium to the right
  • B. Shifts equilibrium to the left
  • C. No effect on equilibrium
  • D. Increases the rate of the forward reaction
Q. In an exothermic reaction, what happens to the enthalpy of the system?
  • A. It increases.
  • B. It decreases.
  • C. It remains constant.
  • D. It becomes zero.
Q. In an isothermal process for an ideal gas, if the volume of the gas is doubled, what happens to the pressure?
  • A. It doubles
  • B. It halves
  • C. It remains constant
  • D. It quadruples
Q. In an isothermal process, which of the following statements is true?
  • A. The temperature remains constant.
  • B. The internal energy changes.
  • C. Work done is zero.
  • D. Heat transfer is zero.
Q. In electrochemical cells, what does the salt bridge do?
  • A. Facilitates electron flow
  • B. Maintains charge balance
  • C. Increases reaction rate
  • D. Prevents gas buildup
Q. In electrochemical cells, what is the role of the cathode?
  • A. Site of oxidation
  • B. Site of reduction
  • C. Source of electrons
  • D. None of the above
Q. In electrochemical sensors, what is typically measured?
  • A. Current
  • B. Voltage
  • C. Resistance
  • D. Temperature
Q. In electrochemistry, what does the Nernst equation relate to?
  • A. Concentration and pressure
  • B. Temperature and volume
  • C. Cell potential and concentration
  • D. Mass and energy
Q. In electrochemistry, what does the term 'Faradaic current' refer to?
  • A. Current due to capacitive effects
  • B. Current due to non-Faradaic processes
  • C. Current associated with redox reactions
  • D. Current due to thermal effects
Q. In electrolysis, the substance that is reduced is found at the:
  • A. Anode
  • B. Cathode
  • C. Electrolyte
  • D. Separator
Q. In electrolysis, what happens to the ions in the electrolyte?
  • A. They remain unchanged.
  • B. They are oxidized or reduced at the electrodes.
  • C. They evaporate into gas.
  • D. They form a solid precipitate.
Q. In electrolysis, what is produced at the cathode?
  • A. Oxygen gas
  • B. Hydrogen gas
  • C. Metal ions
  • D. Salt
Q. In electrolysis, what occurs at the cathode?
  • A. Oxidation
  • B. Reduction
  • C. Neutralization
  • D. Decomposition
Q. In electroplating, what is the purpose of the metal ions in the solution?
  • A. To provide a source of electrons
  • B. To deposit metal onto a surface
  • C. To increase conductivity
  • D. To act as a catalyst
Q. In fuel cells, what is the role of the anode?
  • A. Oxidation of fuel
  • B. Reduction of oxygen
  • C. Storage of energy
  • D. Heat generation
Q. In quantum chemistry, what does the wave function describe?
  • A. The position of a particle.
  • B. The energy of a system.
  • C. The probability distribution of a particle.
  • D. The momentum of a particle.
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