Q. Which application of electrochemistry is used for corrosion prevention?
-
A.
Anodic protection
-
B.
Cathodic protection
-
C.
Electrolysis
-
D.
Electroplating
Solution
Cathodic protection prevents corrosion by making the metal surface the cathode in an electrochemical cell.
Correct Answer:
B
— Cathodic protection
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Q. Which aromatic compound is most reactive towards electrophilic substitution?
-
A.
Benzene
-
B.
Toluene
-
C.
Nitrobenzene
-
D.
Chlorobenzene
Solution
Toluene is more reactive than benzene due to the electron-donating effect of the methyl group, which stabilizes the sigma complex.
Correct Answer:
B
— Toluene
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Q. Which biomolecule is primarily responsible for energy storage in cells?
-
A.
Proteins
-
B.
Nucleic acids
-
C.
Carbohydrates
-
D.
Lipids
Solution
Lipids, particularly triglycerides, are primarily responsible for energy storage in cells.
Correct Answer:
D
— Lipids
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Q. Which biomolecule is primarily responsible for energy storage in living organisms?
-
A.
Proteins
-
B.
Carbohydrates
-
C.
Lipids
-
D.
Nucleic acids
Solution
Lipids are primarily responsible for energy storage in living organisms due to their high energy content.
Correct Answer:
C
— Lipids
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Q. Which compound is an example of a ketone?
-
A.
CH3-CO-CH3
-
B.
CH3-CHO
-
C.
C2H5OH
-
D.
C3H7COOH
Solution
CH3-CO-CH3 is a ketone because it has a carbonyl group (C=O) flanked by two carbon atoms.
Correct Answer:
A
— CH3-CO-CH3
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Q. Which compound is formed when hydrogen reacts with chlorine?
-
A.
Hydrochloric acid
-
B.
Hydrogen chloride
-
C.
Chlorine gas
-
D.
Chlorinated hydrocarbons
Solution
When hydrogen reacts with chlorine, hydrogen chloride (HCl) is formed, which is a gas at room temperature.
Correct Answer:
B
— Hydrogen chloride
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Q. Which coordination compound has a square planar geometry?
-
A.
[Cu(NH3)4]2+
-
B.
[Ni(CN)4]2-
-
C.
[CoCl4]2-
-
D.
[Fe(H2O)6]3+
Solution
The complex [Ni(CN)4]2- has a square planar geometry due to the presence of d8 metal ion.
Correct Answer:
B
— [Ni(CN)4]2-
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Q. Which electrochemical process is essential for the operation of a galvanic cell?
-
A.
Spontaneous redox reaction
-
B.
Electrolysis
-
C.
Thermal decomposition
-
D.
Photovoltaic effect
Solution
A galvanic cell operates based on spontaneous redox reactions that generate electrical energy from chemical energy.
Correct Answer:
A
— Spontaneous redox reaction
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Q. Which electrochemical process is used in electroplating?
-
A.
Reduction
-
B.
Oxidation
-
C.
Sublimation
-
D.
Condensation
Solution
Electroplating involves the reduction of metal cations from a solution to deposit a layer of metal onto a surface.
Correct Answer:
A
— Reduction
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Q. Which electrochemical technique is commonly used for the detection of glucose in blood?
-
A.
Potentiometry
-
B.
Voltammetry
-
C.
Conductometry
-
D.
Spectrophotometry
Solution
Voltammetry is often used in glucose sensors, where the current is measured as a function of applied voltage to determine glucose concentration.
Correct Answer:
B
— Voltammetry
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Q. Which electrophoresis technique is best suited for separating nucleic acids?
-
A.
Capillary Electrophoresis
-
B.
Gel Electrophoresis
-
C.
Isoelectric Focusing
-
D.
Two-Dimensional Electrophoresis
Solution
Gel Electrophoresis is commonly used for the separation of nucleic acids based on size.
Correct Answer:
B
— Gel Electrophoresis
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Q. Which element has the highest electronegativity?
-
A.
Fluorine
-
B.
Oxygen
-
C.
Chlorine
-
D.
Nitrogen
Solution
Fluorine has the highest electronegativity value of 3.98 on the Pauling scale.
Correct Answer:
A
— Fluorine
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Q. Which element has the highest first ionization energy?
-
A.
Helium
-
B.
Neon
-
C.
Argon
-
D.
Krypton
Solution
Helium has the highest first ionization energy due to its small size and high effective nuclear charge.
Correct Answer:
A
— Helium
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Q. Which element has the smallest atomic radius?
-
A.
Helium
-
B.
Hydrogen
-
C.
Lithium
-
D.
Beryllium
Solution
Helium has the smallest atomic radius due to its high effective nuclear charge and minimal electron shielding.
Correct Answer:
A
— Helium
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Q. Which element is most likely to form a cation with a +1 charge?
-
A.
Magnesium
-
B.
Potassium
-
C.
Calcium
-
D.
Aluminum
Solution
Potassium is an alkali metal and typically forms a +1 cation by losing one electron.
Correct Answer:
B
— Potassium
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Q. Which equation accounts for the volume occupied by gas molecules in real gases?
-
A.
Ideal Gas Law
-
B.
Van der Waals equation
-
C.
Boyle's Law
-
D.
Charles's Law
Solution
The Van der Waals equation accounts for the volume occupied by gas molecules and the intermolecular forces in real gases.
Correct Answer:
B
— Van der Waals equation
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Q. Which equation describes the change in internal energy for an ideal gas during an isothermal process?
-
A.
ΔU = 0
-
B.
ΔU = Q + W
-
C.
ΔU = nC_vΔT
-
D.
ΔU = nRΔT
Solution
In an isothermal process for an ideal gas, the temperature remains constant, thus the change in internal energy (ΔU) is zero.
Correct Answer:
A
— ΔU = 0
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Q. Which equation describes the change in internal energy for an ideal gas?
-
A.
ΔU = Q + W
-
B.
ΔU = nC_vΔT
-
C.
ΔU = nRT
-
D.
ΔU = PV
Solution
For an ideal gas, the change in internal energy (ΔU) is given by ΔU = nC_vΔT, where C_v is the molar heat capacity at constant volume.
Correct Answer:
B
— ΔU = nC_vΔT
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Q. Which equation relates the change in enthalpy to heat at constant pressure?
-
A.
ΔH = ΔU + W
-
B.
ΔH = q + PΔV
-
C.
ΔH = q_p
-
D.
ΔH = q_v
Solution
At constant pressure, the change in enthalpy (ΔH) is equal to the heat added to the system (q_p).
Correct Answer:
C
— ΔH = q_p
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Q. Which factor does NOT affect the behavior of real gases?
-
A.
Temperature
-
B.
Pressure
-
C.
Volume
-
D.
Color
Solution
Color does not affect the behavior of real gases; temperature, pressure, and volume are the primary factors.
Correct Answer:
D
— Color
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Q. Which factor does NOT affect the conductivity of an electrolyte solution?
-
A.
Concentration of ions
-
B.
Temperature
-
C.
Nature of solvent
-
D.
Color of solution
Solution
The color of the solution does not affect the conductivity of an electrolyte solution.
Correct Answer:
D
— Color of solution
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Q. Which factor does NOT affect the rate of a chemical reaction?
-
A.
Concentration of reactants
-
B.
Temperature
-
C.
Presence of a catalyst
-
D.
Color of reactants
Solution
The color of reactants does not influence the rate of a chemical reaction, while concentration, temperature, and catalysts do.
Correct Answer:
D
— Color of reactants
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Q. Which factor does NOT affect the rate of an electrochemical reaction?
-
A.
Concentration of reactants
-
B.
Temperature
-
C.
Surface area of electrodes
-
D.
Color of the solution
Solution
The color of the solution does not affect the rate of an electrochemical reaction.
Correct Answer:
D
— Color of the solution
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Q. Which functional group characterizes phenols?
-
A.
Aldehyde
-
B.
Ketone
-
C.
Hydroxyl
-
D.
Carboxyl
Solution
Phenols are characterized by the presence of a hydroxyl (-OH) group attached to an aromatic ring.
Correct Answer:
C
— Hydroxyl
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Q. Which functional group is characteristic of alcohols?
-
A.
Aldehyde
-
B.
Hydroxyl
-
C.
Carboxyl
-
D.
Amine
Solution
The hydroxyl group (-OH) is the functional group characteristic of alcohols.
Correct Answer:
B
— Hydroxyl
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Q. Which functional group is characterized by a carbonyl group (C=O) bonded to a hydroxyl group (–OH)?
-
A.
Alcohol
-
B.
Aldehyde
-
C.
Carboxylic acid
-
D.
Ketone
Solution
A carboxylic acid contains a carbonyl group bonded to a hydroxyl group.
Correct Answer:
C
— Carboxylic acid
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Q. Which functional group is formed in the addition reaction of an alkene with HBr?
-
A.
Alcohol
-
B.
Alkane
-
C.
Alkyl halide
-
D.
Ether
Solution
The addition of HBr to an alkene results in the formation of an alkyl halide.
Correct Answer:
C
— Alkyl halide
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Q. Which functional group is formed when an alcohol reacts with a carboxylic acid?
-
A.
Ester
-
B.
Amide
-
C.
Ether
-
D.
Aldehyde
Solution
The reaction between an alcohol and a carboxylic acid forms an ester through a condensation reaction.
Correct Answer:
A
— Ester
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Q. Which functional group is formed when an alcohol undergoes dehydration?
-
A.
Ether
-
B.
Alkene
-
C.
Alkyne
-
D.
Aldehyde
Solution
Dehydration of an alcohol results in the formation of an alkene by the elimination of water.
Correct Answer:
B
— Alkene
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Q. Which functional group is present in aldehydes?
-
A.
-CHO
-
B.
-COOH
-
C.
-OH
-
D.
-C=O
Solution
Aldehydes contain the carbonyl group (-CHO) at the end of the carbon chain.
Correct Answer:
A
— -CHO
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