Physical Chemistry

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Q. If the equilibrium constant Kc for the reaction A + B ⇌ C is 4 at 25°C, what will be the value of Kc if the concentration of A is doubled?
  • A. 1
  • B. 2
  • C. 4
  • D. 8
Q. If the equilibrium constant Kc for the reaction A ⇌ B is 0.1, what can be inferred about the concentrations of A and B at equilibrium?
  • A. A > B
  • B. A < B
  • C. A = B
  • D. Cannot be determined
Q. If the equilibrium constant Kp for the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g) is 25 at a certain temperature, what is Kp if the volume of the system is halved?
  • A. 12.5
  • B. 25
  • C. 50
  • D. 100
Q. If the half-life of a first-order reaction is 10 minutes, what is the rate constant k?
  • A. 0.0693 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. If the half-life of a first-order reaction is 10 minutes, what is the rate constant?
  • A. 0.0692 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. If the rate constant of a reaction doubles when the temperature increases by 10°C, what is the approximate activation energy (Ea) of the reaction?
  • A. 20 kJ/mol
  • B. 40 kJ/mol
  • C. 60 kJ/mol
  • D. 80 kJ/mol
Q. If the rate constant of a reaction doubles when the temperature increases by 10°C, what is the approximate activation energy?
  • A. 20 kJ/mol
  • B. 40 kJ/mol
  • C. 60 kJ/mol
  • D. 80 kJ/mol
Q. If the rate of a reaction doubles when the concentration of reactant A is tripled, what is the order of the reaction with respect to A?
  • A. 0
  • B. 1
  • C. 2
  • D. 3
Q. If the rate of a reaction doubles when the temperature increases from 300 K to 310 K, what is the approximate activation energy (Ea) in kJ/mol?
  • A. 20.8
  • B. 40.8
  • C. 60.8
  • D. 80.8
Q. If the rate of a reaction is 0.05 M/s when the concentration of reactant A is 0.1 M, what is the rate constant k for a first-order reaction?
  • A. 0.5 s^-1
  • B. 1.0 s^-1
  • C. 0.05 s^-1
  • D. 0.1 s^-1
Q. If the rate of a reaction is proportional to the square of the concentration of reactant A, what is the rate law?
  • A. rate = k[A]
  • B. rate = k[A]^2
  • C. rate = k[A]^3
  • D. rate = k[A]^0
Q. If the rate of a reaction is tripled when the concentration of reactant A is doubled, what is the order of the reaction with respect to A?
  • A. 0
  • B. 1
  • C. 2
  • D. 3
Q. If the standard reduction potential for the half-reaction Fe³⁺ + 3e⁻ → Fe is +0.77 V, what is the potential when [Fe³⁺] = 0.001 M?
  • A. 0.77 V
  • B. 0.70 V
  • C. 0.60 V
  • D. 0.50 V
Q. If the temperature of an exothermic reaction at equilibrium is increased, what is the expected effect on the equilibrium position?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Reaction rate increases
Q. If the temperature of an exothermic reaction at equilibrium is increased, what will happen to the equilibrium position?
  • A. Shift to the right
  • B. Shift to the left
  • C. No change
  • D. Reaction rate increases
Q. If the temperature of an exothermic reaction at equilibrium is increased, what will be the effect on the equilibrium position?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Reaction rate increases
Q. If the temperature of an exothermic reaction at equilibrium is increased, what will happen?
  • A. The equilibrium shifts to the right
  • B. The equilibrium shifts to the left
  • C. No change occurs
  • D. The reaction rate increases
Q. If the temperature of an exothermic reaction is increased, what is the expected effect on the equilibrium?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Reaction rate increases
Q. If the temperature of an exothermic reaction is increased, what will happen to the equilibrium?
  • A. Shift to the right
  • B. Shift to the left
  • C. No change
  • D. Reaction rate increases
Q. If the temperature of the exothermic reaction A + B ⇌ C + heat is increased, what will be the effect on the equilibrium position?
  • A. Shift to the left
  • B. Shift to the right
  • C. No change
  • D. Increase the rate of reaction
Q. In a calorimetry experiment, if 100 g of water absorbs 4200 J of heat, what is the change in temperature assuming no heat loss?
  • A. 1 °C
  • B. 2 °C
  • C. 3 °C
  • D. 4 °C
Q. In a calorimetry experiment, if 50 g of water is heated from 25 °C to 75 °C, what is the heat absorbed (q) assuming specific heat capacity of water is 4.18 J/g°C?
  • A. 1045 J
  • B. 2090 J
  • C. 1250 J
  • D. 500 J
Q. In a calorimetry experiment, what does a negative q value indicate?
  • A. Heat is absorbed by the system.
  • B. Heat is released by the system.
  • C. No heat exchange occurs.
  • D. The reaction is at equilibrium.
Q. In a calorimetry experiment, what does a negative ΔH indicate?
  • A. The reaction is endothermic.
  • B. The reaction is exothermic.
  • C. No heat exchange occurs.
  • D. The system is at equilibrium.
Q. In a calorimetry experiment, what does a positive q value indicate?
  • A. Heat is released by the system
  • B. Heat is absorbed by the system
  • C. No heat exchange occurs
  • D. The system is at equilibrium
Q. In a chemical equilibrium, what does a large equilibrium constant (K) indicate?
  • A. Products are favored at equilibrium
  • B. Reactants are favored at equilibrium
  • C. Equilibrium is not established
  • D. Reaction is slow
Q. In a chemical reaction, if the enthalpy change (ΔH) is negative, what does this indicate?
  • A. The reaction is endothermic
  • B. The reaction is exothermic
  • C. The reaction is at equilibrium
  • D. The reaction requires energy input
Q. In a chemical reaction, if ΔH is negative, the reaction is classified as:
  • A. Endothermic
  • B. Exothermic
  • C. Isothermal
  • D. Adiabatic
Q. In a closed container, if the temperature of a gas is increased, what happens to the pressure if the volume remains constant?
  • A. Pressure decreases
  • B. Pressure remains constant
  • C. Pressure increases
  • D. Pressure fluctuates
Q. In a closed container, if the temperature of a gas is increased, what happens to its pressure?
  • A. Pressure decreases
  • B. Pressure increases
  • C. Pressure remains constant
  • D. Pressure fluctuates
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