Chemistry (School & UG)

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Q. If a reaction at equilibrium is disturbed by removing a product, what will occur?
  • A. Equilibrium shifts to the right
  • B. Equilibrium shifts to the left
  • C. No change in equilibrium position
  • D. Reaction stops
Q. If a reaction is at equilibrium and the volume of the container is decreased, what will happen?
  • A. Shift to the side with more moles of gas
  • B. Shift to the side with fewer moles of gas
  • C. No effect
  • D. Reaction stops
Q. If a sample absorbs light at 250 nm with an absorbance of 0.5, what is the transmittance?
  • A. 50%
  • B. 25%
  • C. 75%
  • D. 100%
Q. If a solution has a concentration of 0.1 M and a path length of 1 cm, what is the absorbance if ε = 200 L/(mol·cm)?
  • A. 20
  • B. 0.2
  • C. 2
  • D. 200
Q. If a system at equilibrium is disturbed by adding a product, what is the expected outcome?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Increases the reaction rate
Q. If the activation energy of a reaction is 50 kJ/mol, what is the effect of increasing the temperature from 300 K to 350 K on the rate constant?
  • A. Rate constant decreases
  • B. Rate constant remains the same
  • C. Rate constant increases
  • D. Rate constant doubles
Q. If the atomic radius of chlorine is 99 pm, what is the atomic radius of potassium in pm?
  • A. 227 pm
  • B. 196 pm
  • C. 186 pm
  • D. 210 pm
Q. If the bond length of a C-C bond is 1.54 Å, what is the bond energy in kJ/mol if the bond order is 1?
  • A. 348
  • B. 612
  • C. 436
  • D. 298
Q. If the concentration of a reactant is halved in a first-order reaction, what happens to the rate?
  • A. Rate is halved
  • B. Rate is doubled
  • C. Rate remains the same
  • D. Rate is quartered
Q. If the concentration of Cu²⁺ in a cell is 0.01 M and the standard reduction potential is +0.34 V, what is the cell potential at 25°C using the Nernst equation?
  • A. 0.34 V
  • B. 0.30 V
  • C. 0.28 V
  • D. 0.25 V
Q. If the concentration of reactants in a redox reaction is doubled, how does it affect the cell potential according to the Nernst equation?
  • A. Increases
  • B. Decreases
  • C. Remains the same
  • D. Depends on temperature
Q. If the enthalpy change (ΔH) for a reaction is -150 kJ and the reaction occurs at constant pressure, how much heat is released when 3 moles of reactants are consumed?
  • A. 50 kJ
  • B. 150 kJ
  • C. 450 kJ
  • D. 300 kJ
Q. If the enthalpy change for a reaction is +75 kJ for 2 moles, what is the enthalpy change per mole?
  • A. 37.5 kJ
  • B. 75 kJ
  • C. 150 kJ
  • D. 25 kJ
Q. If the enthalpy change for a reaction is -500 kJ for 5 moles, what is the enthalpy change for 1 mole?
  • A. 100 kJ
  • B. 500 kJ
  • C. 200 kJ
  • D. 50 kJ
Q. If the enthalpy of formation of CO2(g) is -393.5 kJ/mol, what is the enthalpy change for the combustion of 1 mole of carbon?
  • A. -393.5 kJ
  • B. 393.5 kJ
  • C. 0 kJ
  • D. 786.0 kJ
Q. If the equilibrium constant Kc for the reaction A + B ⇌ C is 4 at 25°C, what will be the value of Kc if the concentration of A is doubled?
  • A. 1
  • B. 2
  • C. 4
  • D. 8
Q. If the equilibrium constant Kc for the reaction A ⇌ B is 0.1, what can be inferred about the concentrations of A and B at equilibrium?
  • A. A > B
  • B. A < B
  • C. A = B
  • D. Cannot be determined
Q. If the equilibrium constant Kp for the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g) is 25 at a certain temperature, what is Kp if the volume of the system is halved?
  • A. 12.5
  • B. 25
  • C. 50
  • D. 100
Q. If the half-life of a first-order reaction is 10 minutes, what is the rate constant?
  • A. 0.0692 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. If the half-life of a first-order reaction is 10 minutes, what is the rate constant k?
  • A. 0.0693 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. If the rate constant of a reaction doubles when the temperature increases by 10°C, what is the approximate activation energy?
  • A. 20 kJ/mol
  • B. 40 kJ/mol
  • C. 60 kJ/mol
  • D. 80 kJ/mol
Q. If the rate constant of a reaction doubles when the temperature increases by 10°C, what is the approximate activation energy (Ea) of the reaction?
  • A. 20 kJ/mol
  • B. 40 kJ/mol
  • C. 60 kJ/mol
  • D. 80 kJ/mol
Q. If the rate of a reaction doubles when the concentration of reactant A is tripled, what is the order of the reaction with respect to A?
  • A. 0
  • B. 1
  • C. 2
  • D. 3
Q. If the rate of a reaction doubles when the temperature increases from 300 K to 310 K, what is the approximate activation energy (Ea) in kJ/mol?
  • A. 20.8
  • B. 40.8
  • C. 60.8
  • D. 80.8
Q. If the rate of a reaction is 0.05 M/s when the concentration of reactant A is 0.1 M, what is the rate constant k for a first-order reaction?
  • A. 0.5 s^-1
  • B. 1.0 s^-1
  • C. 0.05 s^-1
  • D. 0.1 s^-1
Q. If the rate of a reaction is proportional to the square of the concentration of reactant A, what is the rate law?
  • A. rate = k[A]
  • B. rate = k[A]^2
  • C. rate = k[A]^3
  • D. rate = k[A]^0
Q. If the rate of a reaction is tripled when the concentration of reactant A is doubled, what is the order of the reaction with respect to A?
  • A. 0
  • B. 1
  • C. 2
  • D. 3
Q. If the standard reduction potential for the half-reaction Fe³⁺ + 3e⁻ → Fe is +0.77 V, what is the potential when [Fe³⁺] = 0.001 M?
  • A. 0.77 V
  • B. 0.70 V
  • C. 0.60 V
  • D. 0.50 V
Q. If the temperature of an exothermic reaction at equilibrium is increased, what is the expected effect on the equilibrium position?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Reaction rate increases
Q. If the temperature of an exothermic reaction at equilibrium is increased, what will happen to the equilibrium position?
  • A. Shift to the right
  • B. Shift to the left
  • C. No change
  • D. Reaction rate increases
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