The Analytical Techniques section focuses on the methods and instruments used for qualitative and quantitative chemical analysis, essential for understanding experimental chemistry, material characterization, and laboratory diagnostics. This module is designed for school (Class 11–12) and undergraduate students, with strong emphasis on conceptual clarity, instrumentation basics, and exam relevance.
In this section, you will study:
Classical analytical methods – qualitative analysis, gravimetric and volumetric analysis
Spectroscopic techniques – UV–Visible spectroscopy, IR spectroscopy, NMR (introductory level), and mass spectrometry
Chromatographic methods – paper chromatography, TLC, column chromatography, gas chromatography, and HPLC (basics)
Electroanalytical techniques – conductometry, potentiometry, pH measurement, and electrochemical cells
Thermal and surface analysis (introductory) – TGA, DTA, and DSC (UG level)
Instrumentation principles – working, components, and applications
Data interpretation – spectra analysis, peak identification, and quantitative calculations
NCERT- and UG-aligned explanations, supported by diagrams, numericals, MCQs, assertion–reason questions, and PYQs
The content is structured to bridge theory with laboratory practice, strengthen analytical and interpretation skills, and help students confidently answer instrumentation- and application-based questions in school and undergraduate examinations.
Develop a systematic and practical understanding of Analytical Techniques to master this crucial area of modern Chemistry.
Q. In UV-Vis spectroscopy, what does a shift in the absorption peak indicate?
A.
Change in concentration
B.
Change in pH
C.
Change in molecular structure
D.
Change in temperature
Solution
A shift in the absorption peak in UV-Vis spectroscopy often indicates a change in molecular structure, such as the formation of new bonds or changes in electronic transitions.
Q. In UV-Vis spectroscopy, what is the effect of increasing the path length of the sample cell?
A.
Decreases absorbance
B.
Increases absorbance
C.
No effect on absorbance
D.
Increases transmittance
Solution
Increasing the path length of the sample cell increases the absorbance according to the Beer-Lambert Law, as absorbance is directly proportional to path length.
Q. What does the term 'Beer-Lambert Law' describe?
A.
The relationship between temperature and absorbance
B.
The relationship between concentration and absorbance
C.
The relationship between wavelength and absorbance
D.
The relationship between time and absorbance
Solution
The Beer-Lambert Law describes the linear relationship between the concentration of a solute in a solution and the absorbance of light at a specific wavelength.
Correct Answer:
B
— The relationship between concentration and absorbance
A.
Titration of a solution with a known concentration
B.
Titration where the endpoint is determined by color change
C.
Titration of an excess reagent followed by titration of the excess
D.
Titration that uses a solid reagent
Solution
A back titration involves adding an excess of a reagent to react with the analyte, then titrating the excess reagent to determine the amount that reacted.
Correct Answer:
C
— Titration of an excess reagent followed by titration of the excess
Q. What is a common mistake when performing a titration?
A.
Not swirling the flask
B.
Using too much titrant
C.
Not recording the initial volume
D.
All of the above
Solution
Common mistakes in titration include not swirling the flask to ensure proper mixing, using too much titrant, and failing to record the initial volume accurately.