Physical Chemistry

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Q. Which of the following statements about the enthalpy of formation is true?
  • A. It is always negative.
  • B. It is the enthalpy change when one mole of a compound is formed from its elements.
  • C. It can be calculated using Hess's law only.
  • D. It is independent of the physical state of the reactants.
Q. Which of the following statements about the ideal gas law is true?
  • A. It applies to all gases under all conditions
  • B. It is derived from empirical observations
  • C. It is only valid at high pressures
  • D. It assumes no intermolecular forces
Q. Which of the following statements about the phase diagram of a substance is true?
  • A. The triple point is where all three phases coexist
  • B. The critical point is where the solid and liquid phases coexist
  • C. The vapor pressure curve separates solid and liquid phases
  • D. The sublimation curve separates liquid and gas phases
Q. Which of the following statements is true about a concentration cell?
  • A. Has different electrodes
  • B. Has the same electrodes
  • C. Is always at equilibrium
  • D. Requires a salt bridge
Q. Which of the following statements is true about ideal gases?
  • A. They have no volume.
  • B. They have strong intermolecular forces.
  • C. They behave according to the Ideal Gas Law at all conditions.
  • D. They can be liquefied at high temperatures.
Q. Which of the following statements is true about the first law of thermodynamics?
  • A. Energy can be created or destroyed.
  • B. Energy can only be transformed from one form to another.
  • C. The total energy of a closed system decreases.
  • D. Heat and work are the same.
Q. Which of the following statements is true about the phase transition from liquid to gas?
  • A. It is an exothermic process
  • B. It requires energy input
  • C. It occurs at constant pressure only
  • D. It decreases entropy
Q. Which of the following statements is true regarding enthalpy changes?
  • A. Enthalpy changes are path-dependent.
  • B. Enthalpy is a state function.
  • C. Enthalpy cannot be measured directly.
  • D. All of the above.
Q. Which of the following statements is true regarding the enthalpy of a system?
  • A. Enthalpy is a state function.
  • B. Enthalpy depends on the path taken.
  • C. Enthalpy cannot be measured directly.
  • D. Enthalpy is always positive.
Q. Which of the following statements is true regarding the phase diagram of a substance?
  • A. The triple point is where all three phases coexist
  • B. The critical point is where the solid and liquid phases coexist
  • C. The vapor pressure curve separates solid and liquid phases
  • D. The solid phase is always more stable than the liquid phase
Q. Which principle explains the behavior of gases in a closed container when temperature increases?
  • A. Charles's Law
  • B. Boyle's Law
  • C. Avogadro's Law
  • D. Graham's Law
Q. Which principle explains the behavior of gases in terms of molecular motion?
  • A. Kinetic Molecular Theory
  • B. Le Chatelier's Principle
  • C. Raoult's Law
  • D. Hess's Law
Q. Which principle explains the shift in equilibrium when a stress is applied to a system?
  • A. Le Chatelier's Principle
  • B. Hess's Law
  • C. Raoult's Law
  • D. Gibbs Free Energy
Q. Which quantum number describes the shape of an atomic orbital?
  • A. Principal quantum number (n)
  • B. Azimuthal quantum number (l)
  • C. Magnetic quantum number (m_l)
  • D. Spin quantum number (m_s)
Q. Which trend is observed in ionization energy across a period in the periodic table?
  • A. It decreases
  • B. It increases
  • C. It remains constant
  • D. It fluctuates
Q. Which type of bond is formed by the overlap of p orbitals?
  • A. Sigma bond
  • B. Pi bond
  • C. Delta bond
  • D. Phi bond
Q. Which type of bond is formed by the overlap of two p orbitals?
  • A. Sigma bond
  • B. Pi bond
  • C. Delta bond
  • D. Phi bond
Q. Which type of intermolecular force is primarily responsible for the high boiling point of water?
  • A. Van der Waals
  • B. Dipole-dipole
  • C. Hydrogen bonding
  • D. Ionic
Q. Which type of intermolecular force is the strongest?
  • A. London Dispersion Forces
  • B. Dipole-Dipole Interactions
  • C. Hydrogen Bonds
  • D. Ionic Bonds
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