Q. What is the effect of increasing temperature on the rate of a chemical reaction?
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A.
Decreases the rate
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B.
Increases the rate
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C.
No effect
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D.
Depends on the reaction
Solution
Increasing temperature generally increases the rate of a chemical reaction.
Correct Answer: B — Increases the rate
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Q. What is the effect of increasing the concentration of a reactant in a first-order reaction?
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A.
Rate increases linearly
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B.
Rate decreases
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C.
Rate remains constant
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D.
Rate increases exponentially
Solution
In a first-order reaction, increasing the concentration of a reactant results in a linear increase in the rate.
Correct Answer: A — Rate increases linearly
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Q. What is the effect of increasing the concentration of reactants on the rate of a reaction?
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A.
Rate decreases
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B.
Rate increases
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C.
Rate remains constant
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D.
Rate becomes zero
Solution
Increasing the concentration of reactants generally increases the rate of a reaction.
Correct Answer: B — Rate increases
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Q. What is the effect of increasing the pressure on the rate of a reaction involving gaseous reactants?
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A.
Rate decreases
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B.
Rate increases
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C.
No effect
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D.
Depends on the reaction
Solution
Increasing the pressure increases the concentration of gaseous reactants, which generally increases the rate of reaction.
Correct Answer: B — Rate increases
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Q. What is the integrated rate law for a first-order reaction?
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A.
ln[A] = -kt + ln[A]0
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B.
[A] = [A]0 - kt
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C.
[A] = [A]0e^(-kt)
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D.
1/[A] = kt + 1/[A]0
Solution
The integrated rate law for a first-order reaction is ln[A] = -kt + ln[A]0.
Correct Answer: A — ln[A] = -kt + ln[A]0
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Q. What is the order of the reaction if the rate constant has the unit L/mol·s?
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A.
Zero order
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B.
First order
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C.
Second order
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D.
Third order
Solution
If the rate constant has the unit L/mol·s, the reaction is second order.
Correct Answer: C — Second order
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Q. What is the rate law expression for a reaction with the rate equation rate = k[A]^2[B]?
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A.
rate = k[A][B]
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B.
rate = k[A]^2
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C.
rate = k[A]^2[B]
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D.
rate = k[B]
Solution
The rate law expression is derived directly from the rate equation, which is given as rate = k[A]^2[B].
Correct Answer: C — rate = k[A]^2[B]
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Q. What is the unit of the rate constant for a second-order reaction?
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A.
mol/L·s
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B.
L²/mol²·s
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C.
1/s
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D.
mol/L
Solution
The unit of the rate constant for a second-order reaction is L²/mol²·s.
Correct Answer: B — L²/mol²·s
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Q. Which of the following factors does NOT affect the rate of a chemical reaction?
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A.
Concentration of reactants
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B.
Temperature
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C.
Presence of a catalyst
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D.
Color of the reactants
Solution
The color of the reactants does not affect the rate of a chemical reaction.
Correct Answer: D — Color of the reactants
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Q. Which of the following is a characteristic of a catalyst?
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A.
It is consumed in the reaction
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B.
It increases the activation energy
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C.
It lowers the activation energy
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D.
It changes the equilibrium constant
Solution
A catalyst lowers the activation energy of a reaction, thereby increasing the rate.
Correct Answer: C — It lowers the activation energy
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Q. Which of the following is a characteristic of a first-order reaction?
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A.
Rate is proportional to the square of the concentration
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B.
Rate is independent of concentration
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C.
Rate is directly proportional to concentration
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D.
Rate is inversely proportional to concentration
Solution
In a first-order reaction, the rate is directly proportional to the concentration of the reactant.
Correct Answer: C — Rate is directly proportional to concentration
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Q. Which of the following statements about the Arrhenius equation is true?
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A.
It relates temperature to the rate constant
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B.
It is only applicable to zero-order reactions
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C.
It does not consider activation energy
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D.
It is a linear equation
Solution
The Arrhenius equation relates temperature to the rate constant and includes the activation energy.
Correct Answer: A — It relates temperature to the rate constant
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Q. Which of the following statements about the rate of reaction is true?
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A.
It increases with increasing concentration of reactants.
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B.
It decreases with increasing temperature.
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C.
It is always constant.
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D.
It is independent of the nature of reactants.
Solution
The rate of reaction generally increases with increasing concentration of reactants.
Correct Answer: A — It increases with increasing concentration of reactants.
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Q. Which of the following statements is true about catalysts?
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A.
They are consumed in the reaction
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B.
They increase the activation energy
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C.
They provide an alternative pathway with lower activation energy
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D.
They change the equilibrium constant
Solution
Catalysts provide an alternative pathway with lower activation energy, thus increasing the rate of the reaction without being consumed.
Correct Answer: C — They provide an alternative pathway with lower activation energy
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Q. Which of the following statements is true for an endothermic reaction?
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A.
ΔH is negative
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B.
ΔH is positive
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C.
Activation energy is zero
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D.
It occurs spontaneously
Solution
In an endothermic reaction, the enthalpy change (ΔH) is positive as heat is absorbed.
Correct Answer: B — ΔH is positive
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Q. Which of the following statements is true regarding a catalyst?
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A.
Increases activation energy
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B.
Lowers activation energy
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C.
Changes the equilibrium constant
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D.
Is consumed in the reaction
Solution
A catalyst lowers the activation energy of a reaction, thereby increasing the rate without being consumed.
Correct Answer: B — Lowers activation energy
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Q. Which of the following statements is true regarding catalysts?
-
A.
They are consumed in the reaction
-
B.
They increase the activation energy
-
C.
They provide an alternative pathway
-
D.
They change the equilibrium constant
Solution
Catalysts provide an alternative pathway with a lower activation energy, thus increasing the reaction rate without being consumed.
Correct Answer: C — They provide an alternative pathway
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Q. Which of the following statements is true regarding the activation energy (Ea) of a reaction?
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A.
It is always positive
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B.
It can be negative
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C.
It is independent of temperature
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D.
It is the energy of the products
Solution
The activation energy (Ea) of a reaction is always positive.
Correct Answer: A — It is always positive
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Q. Which of the following statements is true regarding the activation energy?
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A.
It is always positive
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B.
It can be negative
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C.
It is independent of temperature
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D.
It is the energy of products
Solution
Activation energy is always positive as it represents the minimum energy required for a reaction to occur.
Correct Answer: A — It is always positive
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Q. Which of the following statements is true regarding the rate of a reaction?
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A.
It increases with increasing temperature
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B.
It decreases with increasing concentration
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C.
It is constant for all reactions
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D.
It is independent of the nature of reactants
Solution
The rate of a reaction generally increases with increasing temperature.
Correct Answer: A — It increases with increasing temperature
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Q. Which of the following statements is true regarding the rate of reaction?
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A.
It is always constant
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B.
It decreases with time for a reactant
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C.
It increases with time for a product
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D.
Both B and C
Solution
The rate of reaction decreases with time for a reactant and increases with time for a product.
Correct Answer: D — Both B and C
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