Physical Chemistry

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Q. Which of the following gases behaves most ideally?
  • A. Noble gases
  • B. Water vapor
  • C. Carbon dioxide
  • D. Ammonia
Q. Which of the following hybridizations corresponds to a tetrahedral molecular geometry?
  • A. sp
  • B. sp2
  • C. sp3
  • D. dsp3
Q. Which of the following ions has the smallest radius?
  • A. Na+
  • B. Mg2+
  • C. Al3+
  • D. Si4+
Q. Which of the following is a characteristic of a reaction at equilibrium?
  • A. The concentrations of reactants and products are equal
  • B. The rate of the forward reaction equals the rate of the reverse reaction
  • C. The reaction has stopped
  • D. The temperature is constant
Q. Which of the following is a characteristic of real gases compared to ideal gases?
  • A. No intermolecular forces
  • B. Volume of gas particles is negligible
  • C. Attraction between particles
  • D. Obeys gas laws perfectly
Q. Which of the following is a common application of electrochemistry in corrosion prevention?
  • A. Cathodic protection
  • B. Anodic oxidation
  • C. Thermal treatment
  • D. Mechanical reinforcement
Q. Which of the following is a common application of electrolysis?
  • A. Water splitting
  • B. Photosynthesis
  • C. Combustion
  • D. Fermentation
Q. Which of the following is a correct expression for the Gibbs free energy change (ΔG) in terms of enthalpy (ΔH) and entropy (ΔS)?
  • A. ΔG = ΔH - TΔS
  • B. ΔG = TΔS - ΔH
  • C. ΔG = ΔH + TΔS
  • D. ΔG = ΔH + ΔS
Q. Which of the following is a primary battery?
  • A. Lead-acid battery
  • B. Nickel-cadmium battery
  • C. Alkaline battery
  • D. Lithium-ion battery
Q. Which of the following is a primary factor affecting the rate of an electrochemical reaction?
  • A. Temperature
  • B. Pressure
  • C. Concentration
  • D. All of the above
Q. Which of the following is a real-world application of electrochemistry?
  • A. Photosynthesis in plants.
  • B. Corrosion prevention techniques.
  • C. Thermal energy storage.
  • D. Mechanical work in engines.
Q. Which of the following is a real-world application of enthalpy calculations?
  • A. Designing refrigeration systems
  • B. Calculating the pH of solutions
  • C. Determining reaction rates
  • D. Measuring electrical conductivity
Q. Which of the following is a real-world application of the ideal gas law?
  • A. Calculating the pressure in a tire
  • B. Determining the boiling point of water
  • C. Measuring the density of solids
  • D. Predicting reaction rates
Q. Which of the following is NOT a unit of enthalpy?
  • A. Joules
  • B. Kilojoules
  • C. Calories
  • D. Atmospheres
Q. Which of the following molecules exhibits hydrogen bonding?
  • A. CH4
  • B. H2O
  • C. CO2
  • D. N2
Q. Which of the following molecules has a linear geometry?
  • A. CO2
  • B. H2O
  • C. NH3
  • D. CH4
Q. Which of the following molecules has a nonpolar covalent bond?
  • A. HCl
  • B. O2
  • C. NH3
  • D. H2O
Q. Which of the following molecules has a trigonal planar geometry?
  • A. CH4
  • B. BF3
  • C. NH3
  • D. H2O
Q. Which of the following molecules has the highest dipole moment?
  • A. CO2
  • B. H2O
  • C. CH4
  • D. NH3
Q. Which of the following molecules is nonpolar?
  • A. HCl
  • B. CO2
  • C. NH3
  • D. H2O
Q. Which of the following orbitals can hold a maximum of 10 electrons?
  • A. s
  • B. p
  • C. d
  • D. f
Q. Which of the following processes is an example of an endothermic reaction?
  • A. Combustion of gasoline
  • B. Dissolving ammonium nitrate in water
  • C. Formation of water from hydrogen and oxygen
  • D. Respiration in living organisms
Q. Which of the following processes is associated with a positive enthalpy change?
  • A. Combustion.
  • B. Dissolution of salts in water.
  • C. Melting of ice.
  • D. Condensation of steam.
Q. Which of the following reactions occurs at the cathode?
  • A. Oxidation
  • B. Reduction
  • C. Electron loss
  • D. Ionization
Q. Which of the following statements about corrosion is true?
  • A. It is a spontaneous redox reaction
  • B. It requires an external power source
  • C. It only occurs in acidic environments
  • D. It is always a slow process
Q. Which of the following statements about electrochemical cells is true?
  • A. They convert chemical energy to electrical energy
  • B. They only work in acidic solutions
  • C. They cannot be reversed
  • D. They require a vacuum to operate
Q. Which of the following statements about electrolysis is true?
  • A. It requires a spontaneous reaction
  • B. It is an endothermic process
  • C. It involves the decomposition of a compound
  • D. It occurs in a galvanic cell
Q. Which of the following statements about ionic bonds is true?
  • A. They involve sharing of electrons.
  • B. They are formed between two nonmetals.
  • C. They result from the transfer of electrons.
  • D. They are weaker than covalent bonds.
Q. Which of the following statements about reaction rates is true?
  • A. Reaction rates are always constant
  • B. Reaction rates can change with time
  • C. Reaction rates are independent of temperature
  • D. Reaction rates are only affected by concentration
Q. Which of the following statements about resonance structures is true?
  • A. They represent different molecules
  • B. They have the same energy
  • C. They differ only in the arrangement of electrons
  • D. They cannot be used to describe real molecules
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