Major Competitive Exams

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Q. For a reaction at standard conditions, if ΔG° is positive, what does it indicate?
  • A. The reaction is spontaneous in the forward direction.
  • B. The reaction is non-spontaneous in the forward direction.
  • C. The reaction is at equilibrium.
  • D. The reaction is spontaneous in the reverse direction.
Q. For a reaction with a rate constant k, what is the relationship between the rate of reaction and the concentration of reactants for a first-order reaction?
  • A. Rate = k[A]^2
  • B. Rate = k[A]
  • C. Rate = k[A]^3
  • D. Rate = k[A]^0
Q. For a reaction with a rate constant of 0.02 M⁻¹s⁻¹ and initial concentration of 0.5 M, what is the time taken to reach 0.25 M in a second-order reaction? (2023)
  • A. 25 s
  • B. 50 s
  • C. 10 s
  • D. 20 s
Q. For a reaction with an activation energy of 50 kJ/mol, what is the rate constant at 300 K if R = 8.314 J/(mol·K)? (2022)
  • A. 0.001 M/s
  • B. 0.01 M/s
  • C. 0.1 M/s
  • D. 1 M/s
Q. For a reaction with an activation energy of 50 kJ/mol, what will happen to the rate if the temperature is increased by 20°C? (2022)
  • A. Rate decreases
  • B. Rate remains the same
  • C. Rate increases significantly
  • D. Rate increases slightly
Q. For a reaction with ΔH = 100 kJ and ΔS = 200 J/K, at what temperature will the reaction become spontaneous?
  • A. 500 K
  • B. 250 K
  • C. 200 K
  • D. 100 K
Q. For a reaction with ΔH = 100 kJ/mol and ΔS = 200 J/mol·K, at what temperature will the reaction become spontaneous?
  • A. 500 K
  • B. 250 K
  • C. 200 K
  • D. 100 K
Q. For a reaction with ΔH = 50 kJ/mol and ΔS = 100 J/mol·K, at what temperature will the reaction become spontaneous?
  • A. 500 K
  • B. 250 K
  • C. 1000 K
  • D. 200 K
Q. For a rectangular plate of mass M and dimensions a x b, what is the moment of inertia about an axis through its center and parallel to side a?
  • A. 1/12 Mb^2
  • B. 1/3 Mb^2
  • C. 1/4 Mb^2
  • D. 1/6 Mb^2
Q. For a reversible process, the change in entropy is given by which of the following?
  • A. ΔS = Q/T
  • B. ΔS = W/T
  • C. ΔS = Q + W
  • D. ΔS = 0
Q. For a reversible process, the change in entropy of the system is equal to the heat absorbed divided by the temperature. This is expressed as:
  • A. ΔS = Q/T
  • B. ΔS = T/Q
  • C. ΔS = Q + T
  • D. ΔS = Q - T
Q. For a reversible process, the change in entropy of the system is equal to the heat absorbed divided by the temperature. What is the formula?
  • A. ΔS = Q/T
  • B. ΔS = T/Q
  • C. ΔS = Q*T
  • D. ΔS = Q + T
Q. For a reversible process, the change in entropy of the universe is:
  • A. Zero
  • B. Positive
  • C. Negative
  • D. Undefined
Q. For a reversible process, the efficiency of a Carnot engine is given by which formula?
  • A. 1 - (T2/T1)
  • B. T1/T2
  • C. T2/T1
  • D. 1 - (T1/T2)
Q. For a satellite in a circular orbit, which of the following is true about its kinetic and potential energy?
  • A. K.E. = P.E.
  • B. K.E. > P.E.
  • C. K.E. < P.E.
  • D. K.E. = 0
Q. For a satellite in a low Earth orbit, what is the approximate altitude range? (2000)
  • A. 200-2000 km
  • B. 500-10000 km
  • C. 1000-20000 km
  • D. 30000-40000 km
Q. For a satellite in a stable orbit, what must be true about the centripetal force and gravitational force?
  • A. Centripetal force is greater than gravitational force
  • B. Centripetal force is less than gravitational force
  • C. Centripetal force equals gravitational force
  • D. Centripetal force is independent of gravitational force
Q. For a single slit of width 'a', what is the angular position of the first minimum?
  • A. λ/a
  • B. a/λ
  • C. sin θ = λ/a
  • D. tan θ = λ/a
Q. For a solenoid of length L and n turns per unit length carrying current I, what is the magnetic field inside the solenoid?
  • A. μ₀nI
  • B. μ₀I/n
  • C. μ₀I/L
  • D. μ₀nI/L
Q. For a solenoid of length L, radius R, and carrying current I, what is the magnetic field inside the solenoid?
  • A. μ₀nI
  • B. μ₀I/L
  • C. μ₀I/2L
  • D. μ₀I/4L
Q. For a solid disk of mass M and radius R, what is the moment of inertia about an axis through its center and perpendicular to its plane?
  • A. 1/2 MR^2
  • B. 1/4 MR^2
  • C. MR^2
  • D. 3/4 MR^2
Q. For a solid disk of mass M and radius R, what is the moment of inertia about an axis perpendicular to the disk and passing through its center?
  • A. 1/2 MR^2
  • B. 1/4 MR^2
  • C. MR^2
  • D. 3/4 MR^2
Q. For a solution containing 2 components A and B, if the mole fraction of A is 0.6, what is the vapor pressure of the solution if the vapor pressure of pure A is 100 mmHg?
  • A. 60 mmHg
  • B. 100 mmHg
  • C. 40 mmHg
  • D. 80 mmHg
Q. For a solution to obey Raoult's Law, the interactions between solute and solvent must be:
  • A. Stronger than those in the pure components.
  • B. Weaker than those in the pure components.
  • C. Similar to those in the pure components.
  • D. Non-existent.
Q. For a spherical Gaussian surface of radius R enclosing a charge Q, what is the electric field at a distance 2R from the center?
  • A. Q/4πε₀(2R)²
  • B. Q/4πε₀R²
  • C. Q/4πε₀(2R)³
  • D. 0
Q. For a spontaneous process, the change in entropy of the universe must be:
  • A. Zero
  • B. Positive
  • C. Negative
  • D. Undefined
Q. For a spontaneous process, the change in Gibbs free energy (ΔG) is related to entropy (ΔS) how?
  • A. ΔG = ΔH - TΔS
  • B. ΔG = TΔS - ΔH
  • C. ΔG = ΔS - ΔH
  • D. ΔG = ΔH + TΔS
Q. For a spontaneous process, the change in Gibbs free energy (ΔG) is related to entropy (ΔS) by which of the following equations?
  • A. ΔG = ΔH + TΔS
  • B. ΔG = ΔH - TΔS
  • C. ΔG = TΔS - ΔH
  • D. ΔG = ΔS - ΔH
Q. For a spontaneous process, the change in Gibbs free energy (ΔG) is:
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Undefined
Q. For a system of particles, how is the moment of inertia calculated?
  • A. Sum of individual moments
  • B. Product of mass and distance squared
  • C. Sum of mass times distance squared
  • D. Average of all moments
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