Physical Chemistry

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Q. What is the relationship between pressure and volume in a gas at constant temperature?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Ideal Gas Law
Q. What is the relationship between pressure and volume in an ideal gas at constant temperature?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Graham's Law
Q. What is the relationship between reaction rate and concentration for a first-order reaction?
  • A. Rate is proportional to concentration
  • B. Rate is proportional to the square of concentration
  • C. Rate is independent of concentration
  • D. Rate is inversely proportional to concentration
Q. What is the relationship between the rate constant and temperature according to the Arrhenius equation?
  • A. Rate constant is independent of temperature
  • B. Rate constant increases with temperature
  • C. Rate constant decreases with temperature
  • D. Rate constant is constant at all temperatures
Q. What is the relationship between the rate constant and temperature for a reaction according to the Arrhenius equation?
  • A. k = Ae^(-Ea/RT)
  • B. k = Ea/RT
  • C. k = RTe^(-Ea)
  • D. k = A + Ea/RT
Q. What is the relationship between the rate constant k and temperature T according to the Arrhenius equation?
  • A. k increases with decreasing T
  • B. k decreases with increasing T
  • C. k increases with increasing T
  • D. k is independent of T
Q. What is the relationship between the rate of a reaction and the concentration of reactants in a first-order reaction?
  • A. Rate is proportional to the square of the concentration
  • B. Rate is inversely proportional to the concentration
  • C. Rate is directly proportional to the concentration
  • D. Rate is independent of the concentration
Q. What is the role of a catalyst in a chemical reaction?
  • A. It increases the activation energy
  • B. It decreases the activation energy
  • C. It is consumed in the reaction
  • D. It changes the equilibrium position
Q. What is the role of a cathode in an electrochemical cell?
  • A. It is where oxidation occurs.
  • B. It is where reduction occurs.
  • C. It is where the salt bridge connects.
  • D. It is where the electrons are generated.
Q. What is the role of a salt bridge in an electrochemical cell?
  • A. To connect the two electrodes
  • B. To maintain charge balance
  • C. To increase conductivity
  • D. To provide a source of ions
Q. What is the shape of a molecule with 5 bonding pairs and 1 lone pair?
  • A. Octahedral
  • B. Square Pyramidal
  • C. Trigonal Bipyramidal
  • D. Tetrahedral
Q. What is the shape of the NH4+ ion?
  • A. Linear
  • B. Trigonal Planar
  • C. Tetrahedral
  • D. Octahedral
Q. What is the shape of the PCl5 molecule?
  • A. Trigonal planar
  • B. Tetrahedral
  • C. Trigonal bipyramidal
  • D. Octahedral
Q. What is the significance of the critical point in phase diagrams?
  • A. It indicates the temperature at which a substance boils
  • B. It marks the end of the liquid-gas phase boundary
  • C. It shows the maximum pressure a solid can withstand
  • D. It defines the temperature at which a solid melts
Q. What is the significance of the equilibrium constant (K) in a chemical reaction?
  • A. It indicates the speed of the reaction
  • B. It shows the ratio of products to reactants at equilibrium
  • C. It determines the activation energy
  • D. It measures the change in enthalpy
Q. What is the significance of the Faraday constant in electrochemistry?
  • A. It relates to the energy of a reaction.
  • B. It defines the charge of one mole of electrons.
  • C. It measures the temperature of a reaction.
  • D. It indicates the speed of a reaction.
Q. What is the significance of the Gibbs free energy (G)?
  • A. It indicates the spontaneity of a process.
  • B. It measures the total energy of a system.
  • C. It represents the enthalpy change.
  • D. It is always positive.
Q. What is the significance of the Gibbs free energy change (ΔG)?
  • A. Indicates the spontaneity of a reaction
  • B. Indicates the rate of a reaction
  • C. Indicates the equilibrium position
  • D. Indicates the enthalpy change
Q. What is the significance of the Gibbs free energy in thermodynamics?
  • A. It predicts the direction of spontaneous processes
  • B. It measures the heat content of a system
  • C. It defines the equilibrium constant
  • D. It relates pressure and volume
Q. What is the standard cell potential (E°) for a galvanic cell composed of a zinc electrode and a copper electrode?
  • A. 0.34 V
  • B. 1.10 V
  • C. 0.76 V
  • D. 1.96 V
Q. What is the standard cell potential (E°) for a galvanic cell with half-reactions: Zn²⁺ + 2e⁻ → Zn (E° = -0.76 V) and Cu²⁺ + 2e⁻ → Cu (E° = +0.34 V)?
  • A. -1.10 V
  • B. -0.42 V
  • C. 0.42 V
  • D. 1.10 V
Q. What is the standard electrode potential for the reduction of Ag⁺ to Ag?
  • A. 0.80 V
  • B. 0.46 V
  • C. 0.34 V
  • D. 0.00 V
Q. What is the standard electrode potential of a half-cell reaction?
  • A. A measure of the tendency of a chemical species to be reduced
  • B. A measure of the concentration of ions
  • C. A measure of the temperature of the system
  • D. A measure of the pressure of the system
Q. What is the standard electrode potential of a half-reaction?
  • A. The potential at which the reaction occurs at standard conditions
  • B. The potential at which the reaction occurs at any conditions
  • C. The potential difference between two electrodes
  • D. The energy change of the reaction
Q. What is the standard enthalpy change (ΔH°) for the formation of 1 mole of CO2(g) from C(s) and O2(g) given the following reactions: C(s) + O2(g) → CO2(g) ΔH° = -393.5 kJ?
  • A. -393.5 kJ
  • B. 393.5 kJ
  • C. 0 kJ
  • D. -273.15 kJ
Q. What is the standard enthalpy change for a reaction at equilibrium?
  • A. ΔH = 0
  • B. ΔH < 0
  • C. ΔH > 0
  • D. ΔH is undefined
Q. What is the standard enthalpy change for the combustion of methane (CH4) if ΔHf for CO2(g) is -393.5 kJ/mol and for H2O(l) is -285.8 kJ/mol?
  • A. -890.3 kJ/mol
  • B. 890.3 kJ/mol
  • C. 0 kJ/mol
  • D. 393.5 kJ/mol
Q. What is the standard enthalpy change for the reaction: 2H2(g) + O2(g) → 2H2O(g) if the enthalpy of formation of H2O(g) is -241.8 kJ/mol?
  • A. -483.6 kJ
  • B. 241.8 kJ
  • C. 0 kJ
  • D. 483.6 kJ
Q. What is the standard enthalpy change of a reaction (ΔH°) at standard conditions?
  • A. 1 atm and 25°C
  • B. 1 atm and 0°C
  • C. 2 atm and 25°C
  • D. 1 atm and 100°C
Q. What is the standard enthalpy change of formation (ΔHf°) for elements in their standard state?
  • A. 0 kJ/mol
  • B. 1 kJ/mol
  • C. ΔHf° is always positive
  • D. ΔHf° is always negative
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