Physical Chemistry

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Q. What is the effective nuclear charge (Z_eff) experienced by a 3p electron in phosphorus (atomic number 15)?
  • A. 3
  • B. 5
  • C. 7
  • D. 8
Q. What is the effective nuclear charge (Z_eff) for a 3s electron in sodium (Na)?
  • A. 1
  • B. 3
  • C. 11
  • D. 8
Q. What is the effective nuclear charge (Z_eff) for a 3s electron in sodium (Z=11)?
  • A. 1
  • B. 3
  • C. 8
  • D. 11
Q. What is the electron affinity of chlorine in kJ/mol?
  • A. -349 kJ/mol
  • B. -328 kJ/mol
  • C. -300 kJ/mol
  • D. -400 kJ/mol
Q. What is the electron configuration of a chlorine atom?
  • A. 1s2 2s2 2p6 3s2 3p5
  • B. 1s2 2s2 2p6 3s2 3p6
  • C. 1s2 2s2 2p6 3s2 3p4
  • D. 1s2 2s2 2p6 3s2 3p3
Q. What is the electron configuration of a neutral atom of sulfur (S)?
  • A. [Ne] 3s2 3p4
  • B. [He] 2s2 2p6 3s2 3p4
  • C. [Ar] 4s2 3d10 4p4
  • D. [Ne] 3s2 3p6
Q. What is the electron configuration of a neutral oxygen atom?
  • A. 1s2 2s2 2p4
  • B. 1s2 2s2 2p6
  • C. 1s2 2s2 2p3
  • D. 1s2 2s2 2p5
Q. What is the electron configuration of a neutral sulfur atom?
  • A. 1s2 2s2 2p6 3s2 3p4
  • B. 1s2 2s2 2p6 3s2 3p6
  • C. 1s2 2s2 2p6 3s2 3p3
  • D. 1s2 2s2 2p6 3s2 3p5
Q. What is the electron configuration of the element with atomic number 30?
  • A. [Ar] 4s2 3d10
  • B. [Kr] 5s2 4d10
  • C. [Ar] 4s2 3d8
  • D. [Ar] 4s2 3d9
Q. What is the electron configuration of the ion Fe3+?
  • A. [Ar] 4s2 3d5
  • B. [Ar] 3d5
  • C. [Ar] 4s2 3d3
  • D. [Ar] 3d6
Q. What is the electron configuration of the sulfur ion (S^2-)?
  • A. [Ne] 3s² 3p⁴
  • B. [Ne] 3s² 3p⁶
  • C. [Ne] 3s² 3p³
  • D. [He] 2s² 2p⁶
Q. What is the electron geometry of a molecule with four electron groups around the central atom?
  • A. Linear
  • B. Trigonal planar
  • C. Tetrahedral
  • D. Octahedral
Q. What is the electronegativity difference between sodium (Na) and chlorine (Cl)?
  • A. 0.8
  • B. 1.0
  • C. 2.1
  • D. 3.0
Q. What is the electronegativity of fluorine on the Pauling scale?
  • A. 3.0
  • B. 3.5
  • C. 4.0
  • D. 4.5
Q. What is the enthalpy change (ΔH) for the reaction: 2H2(g) + O2(g) → 2H2O(g) if ΔHf for H2O(g) is -241.8 kJ/mol?
  • A. -483.6 kJ
  • B. 241.8 kJ
  • C. 0 kJ
  • D. 483.6 kJ
Q. What is the enthalpy change for the reaction: C(s) + O2(g) → CO2(g) if the standard enthalpy of formation of CO2 is -393.5 kJ/mol?
  • A. -393.5 kJ/mol
  • B. 393.5 kJ/mol
  • C. 0 kJ/mol
  • D. Not enough information
Q. What is the enthalpy change for the reaction: H2(g) + 1/2 O2(g) → H2O(l) at standard conditions?
  • A. -285.8 kJ/mol
  • B. 0 kJ/mol
  • C. 285.8 kJ/mol
  • D. -241.8 kJ/mol
Q. What is the enthalpy change for the reaction: N2(g) + 3H2(g) → 2NH3(g) if the standard enthalpy of formation of NH3(g) is -45.9 kJ/mol?
  • A. -91.8 kJ
  • B. 45.9 kJ
  • C. 0 kJ
  • D. 91.8 kJ
Q. What is the enthalpy change for the reaction: N2(g) + 3H2(g) → 2NH3(g) if ΔHf° for NH3 is -45.9 kJ/mol?
  • A. -137.7 kJ
  • B. -91.8 kJ
  • C. 0 kJ
  • D. 45.9 kJ
Q. What is the enthalpy change when 2 moles of water vapor condense to liquid water at constant temperature?
  • A. -2ΔH_vap
  • B. 2ΔH_vap
  • C. 0
  • D. ΔH_vap
Q. What is the enthalpy change when 4 moles of a substance release 800 J of heat?
  • A. 200 J/mol
  • B. 400 J/mol
  • C. 100 J/mol
  • D. 300 J/mol
Q. What is the equilibrium constant (K) for a reaction with ΔG° = -40 kJ at 298 K?
  • A. 10
  • B. 100
  • C. 1000
  • D. 10000
Q. What is the equilibrium constant expression for the reaction A + B ⇌ C?
  • A. [C]/([A][B])
  • B. [A][B]/[C]
  • C. [C]^2/([A][B])
  • D. [C]/[A] + [B]
Q. What is the expected bond angle in a molecule with sp2 hybridization?
  • A. 90 degrees
  • B. 120 degrees
  • C. 180 degrees
  • D. 109.5 degrees
Q. What is the expected bond angle in a molecule with tetrahedral geometry?
  • A. 90 degrees
  • B. 109.5 degrees
  • C. 120 degrees
  • D. 180 degrees
Q. What is the expected bond length of a C-C single bond?
  • A. 1.54 Å
  • B. 1.34 Å
  • C. 1.20 Å
  • D. 1.45 Å
Q. What is the Faraday constant approximately equal to?
  • A. 96485 C/mol
  • B. 96500 C/mol
  • C. 100000 C/mol
  • D. 90000 C/mol
Q. What is the first ionization energy of lithium (Li) in kJ/mol?
  • A. 520 kJ/mol
  • B. 750 kJ/mol
  • C. 1000 kJ/mol
  • D. 1500 kJ/mol
Q. What is the first ionization energy of magnesium (Mg) in kJ/mol?
  • A. 738 kJ/mol
  • B. 1000 kJ/mol
  • C. 580 kJ/mol
  • D. 1200 kJ/mol
Q. What is the Gibbs free energy change (ΔG) at 298 K for a reaction with ΔH = -100 kJ and ΔS = -200 J/K?
  • A. -100 kJ
  • B. -200 kJ
  • C. 0 kJ
  • D. 100 kJ
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