Q. In the nitration of benzene, which reagent is used to generate the nitronium ion (NO2+)?
A.
HNO3
B.
H2SO4
C.
HCl
D.
NaNO2
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Solution
Concentrated sulfuric acid (H2SO4) is used to generate the nitronium ion (NO2+) from nitric acid (HNO3) in the nitration of benzene.
Correct Answer:
B
— H2SO4
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Q. In the nitration of toluene, what is the major product formed?
A.
Ortho-nitrotoluene
B.
Para-nitrotoluene
C.
Meta-nitrotoluene
D.
Toluene
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Solution
The major product is para-nitrotoluene due to steric hindrance at the ortho position, making the para position more favorable for substitution.
Correct Answer:
B
— Para-nitrotoluene
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Q. In the nitration of toluene, which position is most likely to be attacked by the electrophile?
A.
Ortho position
B.
Meta position
C.
Para position
D.
All positions equally
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Solution
The para position is favored in the nitration of toluene due to the electron-donating effect of the methyl group, which stabilizes the carbocation intermediate.
Correct Answer:
C
— Para position
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Q. In the nitration of toluene, which position is most likely to be substituted?
A.
Ortho
B.
Meta
C.
Para
D.
All positions equally
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Solution
The para position is most likely to be substituted in the nitration of toluene due to the electron-donating effect of the methyl group.
Correct Answer:
C
— Para
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Q. In the nitration of toluene, which position is predominantly substituted?
A.
Ortho
B.
Meta
C.
Para
D.
All equally
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Solution
The para position is predominantly substituted due to steric hindrance at the ortho position, making the para product more favorable.
Correct Answer:
C
— Para
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Q. In the nitration of toluene, which product is formed predominantly?
A.
Nitrotoluene (ortho)
B.
Nitrotoluene (para)
C.
Dinitrotoluene
D.
Benzyl nitrite
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Solution
The para-nitrotoluene is formed predominantly due to steric hindrance at the ortho position.
Correct Answer:
B
— Nitrotoluene (para)
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Q. In the nitration of toluene, which product is predominantly formed?
A.
Nitrotoluene
B.
Dinitrotoluene
C.
Benzyl alcohol
D.
Toluene sulfonic acid
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Solution
The predominant product is nitrotoluene, specifically ortho- and para-nitrotoluene due to the activating effect of the methyl group.
Correct Answer:
A
— Nitrotoluene
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Q. In the presence of a strong electrophile, which aromatic compound will undergo substitution the fastest?
A.
Benzene
B.
Phenol
C.
Aniline
D.
Toluene
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Solution
Aniline will undergo substitution the fastest due to the strong activating effect of the amino group, which donates electron density to the ring.
Correct Answer:
C
— Aniline
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Q. In the presence of a strong electrophile, which position on a disubstituted benzene ring will a third substituent most likely attach?
A.
Ortho
B.
Meta
C.
Para
D.
Random
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Solution
The position of the third substituent depends on the nature of the existing substituents; however, ortho and para positions are generally favored for activating groups.
Correct Answer:
A
— Ortho
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Q. In the presence of sulfuric acid, what is the product of the electrophilic substitution of benzene with sulfur trioxide?
A.
Benzene sulfonic acid
B.
Benzene thiosulfate
C.
Benzene sulfide
D.
Benzene disulfide
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Solution
The product is benzene sulfonic acid, formed by the electrophilic substitution of sulfur trioxide on benzene.
Correct Answer:
A
— Benzene sulfonic acid
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Q. In the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what happens if the concentration of SO3 is decreased?
A.
Shifts equilibrium to the right
B.
Shifts equilibrium to the left
C.
No effect on equilibrium
D.
Increases the rate of the reverse reaction
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Solution
Decreasing the concentration of SO3 will shift the equilibrium to the right to produce more SO3, according to Le Chatelier's Principle.
Correct Answer:
A
— Shifts equilibrium to the right
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Q. In the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of increasing the concentration of O2?
A.
Shift to the right
B.
Shift to the left
C.
No effect
D.
Increases the rate of reaction
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Solution
Increasing the concentration of O2 will shift the equilibrium to the right, favoring the production of SO3.
Correct Answer:
A
— Shift to the right
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Q. In the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what will happen if SO3 is added?
A.
Shift to the right
B.
Shift to the left
C.
No change
D.
Reaction stops
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Solution
Adding SO3 will shift the equilibrium to the left to favor the formation of reactants, according to Le Chatelier's Principle.
Correct Answer:
B
— Shift to the left
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Q. In the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what will happen if the pressure is increased?
A.
Shifts to the left
B.
Shifts to the right
C.
No effect
D.
Increases the temperature
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Solution
Increasing the pressure will shift the equilibrium to the right, favoring the formation of SO3, as it has fewer moles of gas (2 moles) compared to the reactants (3 moles).
Correct Answer:
B
— Shifts to the right
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Q. In the reaction A(g) + B(g) ⇌ C(g) + D(g), if the volume is increased, what will happen to the equilibrium?
A.
Shifts to the left
B.
Shifts to the right
C.
No effect
D.
Increases the temperature
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Solution
Increasing the volume decreases the pressure, and the equilibrium will shift to the side with more moles of gas to counteract the change.
Correct Answer:
B
— Shifts to the right
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Q. In the reaction A(g) + B(g) ⇌ C(g), if A is removed from the system, what will happen?
A.
Equilibrium shifts to the right
B.
Equilibrium shifts to the left
C.
No change occurs
D.
Reaction stops
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Solution
Removing A will shift the equilibrium to the left to produce more A, according to Le Chatelier's Principle.
Correct Answer:
B
— Equilibrium shifts to the left
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Q. In the reaction A(g) + B(g) ⇌ C(g), if the pressure is increased, which direction will the equilibrium shift if there are more moles of gas on the left?
A.
Shifts to the right
B.
Shifts to the left
C.
No effect
D.
Increases temperature
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Solution
Increasing pressure will shift the equilibrium to the right, favoring the side with fewer moles of gas.
Correct Answer:
A
— Shifts to the right
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Q. In the reaction CO(g) + 2H2(g) ⇌ CH3OH(g), what effect does adding more CO have on the equilibrium?
A.
Shift to the left
B.
Shift to the right
C.
No change
D.
Increase the rate of reaction
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Solution
Adding more CO increases its concentration, which shifts the equilibrium to the right to produce more CH3OH.
Correct Answer:
B
— Shift to the right
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Q. In the reaction CO(g) + 2H2(g) ⇌ CH3OH(g), what is the effect of increasing the pressure?
A.
Shifts to the right
B.
Shifts to the left
C.
No effect
D.
Increases the temperature
Show solution
Solution
Increasing the pressure favors the side with fewer moles of gas. In this case, the right side has fewer moles (1 mole of CH3OH) compared to the left (3 moles), so the equilibrium shifts to the right.
Correct Answer:
A
— Shifts to the right
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Q. In the reaction CO(g) + 2H2(g) ⇌ CH3OH(g), what will happen if the temperature is decreased?
A.
Shifts equilibrium to the right
B.
Shifts equilibrium to the left
C.
No effect on equilibrium
D.
Increases the concentration of H2
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Solution
If the reaction is exothermic, decreasing the temperature will shift the equilibrium to the right to produce more products (CH3OH).
Correct Answer:
A
— Shifts equilibrium to the right
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Q. In the reaction H2(g) + I2(g) ⇌ 2HI(g), what happens if the concentration of HI is increased?
A.
Shift to the left
B.
Shift to the right
C.
No change
D.
Increase the rate of reaction
Show solution
Solution
Increasing the concentration of HI will shift the equilibrium to the left to reduce the concentration of HI, according to Le Chatelier's Principle.
Correct Answer:
A
— Shift to the left
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Q. In the reaction N2(g) + 3H2(g) ⇌ 2NH3(g), if the concentration of NH3 is increased, what will happen to the concentration of N2 at equilibrium?
A.
Increase
B.
Decrease
C.
Remain the same
D.
Cannot be determined
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Solution
According to Le Chatelier's principle, increasing the concentration of a product (NH3) will shift the equilibrium to the left, decreasing N2.
Correct Answer:
B
— Decrease
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Q. In the reaction N2(g) + 3H2(g) ⇌ 2NH3(g), what happens if the concentration of NH3 is decreased?
A.
Equilibrium shifts to the right
B.
Equilibrium shifts to the left
C.
No effect on equilibrium
D.
Reaction stops
Show solution
Solution
Decreasing the concentration of NH3 will shift the equilibrium to the right to produce more NH3, according to Le Chatelier's Principle.
Correct Answer:
A
— Equilibrium shifts to the right
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Q. In the reaction of 2-bromobutane with KOH in ethanol, what type of mechanism is primarily involved?
A.
SN1
B.
SN2
C.
E1
D.
E2
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Solution
The reaction proceeds via an E2 mechanism due to the strong base (KOH) and the presence of a good leaving group (Br).
Correct Answer:
D
— E2
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Q. In the reaction of an alkene with HBr, what is the major product formed?
A.
Alkane
B.
Alkyl bromide
C.
Alcohol
D.
Ether
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Solution
The addition of HBr to an alkene follows Markovnikov's rule, leading to the formation of the more stable alkyl bromide as the major product.
Correct Answer:
B
— Alkyl bromide
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Q. In the reaction of an alkene with HBr, what is the major product when the alkene is asymmetric?
A.
Markovnikov product
B.
Anti-Markovnikov product
C.
No reaction
D.
Polymerization
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Solution
According to Markovnikov's rule, the hydrogen from HBr adds to the less substituted carbon of the alkene, leading to the formation of the Markovnikov product.
Correct Answer:
A
— Markovnikov product
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Q. In the reaction of benzene with bromine in the presence of FeBr3, what type of reaction occurs?
A.
Electrophilic substitution
B.
Nucleophilic substitution
C.
Addition
D.
Elimination
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Solution
This reaction is an electrophilic aromatic substitution where bromine acts as an electrophile.
Correct Answer:
A
— Electrophilic substitution
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Q. In the reaction of benzyl chloride with a strong nucleophile, which mechanism is favored?
A.
SN1
B.
SN2
C.
E1
D.
E2
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Solution
Benzyl chloride can stabilize a carbocation, thus the SN1 mechanism is favored when reacting with a strong nucleophile.
Correct Answer:
A
— SN1
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Q. In the reaction of benzyl chloride with sodium hydroxide, which mechanism is primarily involved?
A.
SN1
B.
SN2
C.
E1
D.
E2
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Solution
The reaction of benzyl chloride with sodium hydroxide primarily follows the SN1 mechanism due to the stability of the benzyl carbocation formed during the reaction.
Correct Answer:
A
— SN1
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Q. In the reaction of cyclohexene with H2 in the presence of a catalyst, what is the expected product?
A.
Cyclohexane
B.
Hexane
C.
Cyclohexanol
D.
1-hexene
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Solution
The hydrogenation of cyclohexene in the presence of a catalyst leads to the formation of cyclohexane.
Correct Answer:
A
— Cyclohexane
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