Topic 2: Assumptions of Kinetic Theory of Gases

Assumptions of Kinetic Theory of Gases

The kinetic theory of gases is based on certain assumptions which help to explain the behaviour of gases.

Main Assumptions

  • Gas consists of a large number of tiny molecules
  • The volume of individual gas molecules is negligible compared to the volume of the container
  • Gas molecules are in continuous random motion
  • Collisions between gas molecules and with container walls are perfectly elastic
  • No intermolecular force of attraction or repulsion exists between gas molecules
  • Gas pressure is due to collisions of molecules with container walls
  • The average kinetic energy of gas molecules is proportional to the absolute temperature

Explanation of Assumptions

Random motion of molecules explains diffusion of gases. Elastic collisions explain conservation of kinetic energy.

Limitations

Kinetic theory is applicable mainly to ideal gases and fails for real gases at high pressure and low temperature.

Q1. According to kinetic theory, gas molecules are:
A) At rest
B) In vibratory motion
C) In continuous random motion
D) In circular motion

Answer: C


Q2. Volume of gas molecules is assumed to be:
A) Very large
B) Equal to container
C) Negligible
D) Infinite

Answer: C


Q3. Collisions between gas molecules are:
A) Inelastic
B) Partially elastic
C) Perfectly elastic
D) Non-elastic

Answer: C


Q4. Pressure of gas is due to:
A) Attraction between molecules
B) Weight of gas
C) Collision of molecules with walls
D) Volume of molecules

Answer: C


Q5. Intermolecular forces between gas molecules are:
A) Strong
B) Weak
C) Attractive
D) Negligible

Answer: D


Q6. Average kinetic energy of gas molecules depends on:
A) Pressure
B) Volume
C) Temperature
D) Mass

Answer: C


Q7. Kinetic theory is applicable mainly to:
A) Real gases
B) Liquids
C) Solids
D) Ideal gases

Answer: D


Q8. Which phenomenon is explained by random motion of gas molecules?
A) Pressure
B) Diffusion
C) Refraction
D) Reflection

Answer: B

Chapter 9: Kinetic Theory of Gases

Topic 2: Assumptions – Quick Revision

Key Assumptions

  • Gas molecules are tiny and far apart
  • Volume of molecules is negligible
  • Molecules are in random motion
  • Collisions are perfectly elastic
  • No intermolecular forces
  • Pressure due to collisions
  • Kinetic energy ∝ absolute temperature

Limitations

Applicable mainly to ideal gases.

Exam Focus (MHT-CET)

Direct MCQs are frequently asked on assumptions and their implications.


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